Electroluminescence (EL)

Probe Light Emission under Electrical Excitation

An optical technique that analyzes light emission under electrical excitation to reveal electronic properties of electroluminescent materials.
Time-resolved electroluminescence decay of LED and quantum dot device
Table of contents

From Electrical Excitation to Emission and Device Insights

What is Electroluminescence (EL)?

Electroluminescence (EL) is an optical characterization technique in which light emission is generated by electrical excitation of a material or device. Under an applied bias, injected charge carriers recombine radiatively, producing photons whose spectral and spatial characteristics reveal the material’s electronic and structural properties. EL measurements are widely employed in the analysis of LEDs, solar cells, and other optoelectronic devices, offering direct insight into charge transport, recombination dynamics, and inhomogeneities under real operating conditions.

How does Electroluminescence (EL) work?

In an electroluminescence (EL) experiment, an electrical voltage or current is applied to a device, driving electrons and holes into the active material layer. When these charge carriers recombine radiatively, photons are emitted. The emitted light is collected and analyzed spectrally, temporally, or spatially to probe the material’s optoelectronic properties. EL measurements can be performed under steady-state or time-resolved conditions, enabling quantitative insights into recombination dynamics, emission efficiency, and spatial uniformity of device performance.

Electroluminescence (EL) Data & Analysis

Electroluminescence (EL) data typically comprise emission spectra, intensity maps, and time-resolved decay traces. Spectral analysis reveals key optoelectronic features such as bandgap energy, defect-related emission, and carrier recombination pathways. Spatially resolved EL imaging identifies inhomogeneities including defects, non-uniform current injection, or degradation sites. Time-resolved EL provides access to carrier lifetimes and recombination dynamics under electrical excitation. Quantitative analysis often correlates EL intensity and spectra with applied bias, current density, or temperature to extract device-relevant parameters.

PicoQuant software for Electroluminescence (EL) analysis

PicoQuant’s EasyTau 2 software enables intuitive TRPL data acquisition and decay analysis, with integrated fitting, reconvolution, and batch processing tools in a single streamlined workflow.

Why use Electroluminescence (EL)?

Electroluminescence directly probes light emission under realistic electrical operating conditions, making it highly relevant for device characterization. It enables the investigation of charge injection, transport, and recombination processes that cannot be accessed by optical excitation alone. EL is particularly valuable for evaluating semiconductor materials, LEDs, OLEDs, and solar cells, as well as for exploring emerging optoelectronic materials. By revealing efficiency losses, defect-induced emission, and spatial inhomogeneities, , EL supports device optimization, failure diagnostics, and the development of next-generation electroluminescent materials.

Instrumentation requirements for Electroluminescence (EL)

Reliable electroluminescence (EL) measurements require stable electrical excitation, sensitive optical detection, and precise synchronization between driving and acquisition systems. Essential components include low-noise voltage or current sources, spectrally calibrated detectors, and high-efficiency optical collection systems optimized for weak emission signals. For time-resolved EL, fast detectors and high-resolution timing electronics are essential to resolve recombination dynamics. Spatially resolved EL relies on imaging optics combined with scanning or camera-based detection. Additional requirements such as temperature control, background suppression, and calibration routines ensure quantitative accuracy and reproducibility.

Relevant for Your Research​

Matching Applications

Image of a solar cell surface structure used for optical characterization of charge carrier dynamics and recombination processes.
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Time-resolved photoluminescence emission spectrum showing three peaks from different semiconductor layers, illustrating layer-specific recombination dynamics.
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Application Examples

CIE 1931 chromaticity diagram showing LED and QD-LED emission coordinates

Time-Resolved Electroluminescence Characterization of a Quantum Dot LED

This application note demonstrates steady-state and time-resolved electroluminescence measurements of a LED and a hybrid QD-LED using the FluoTime 300 spectrometer, revealing emission spectra, chromaticity shifts, and carrier recombination dynamics under electrical excitation.

Related Methods

Excitation and emission spectra of fluorescence polymer reference materials SFG and SFO measured with a microscope-based photoluminescence setup.

Photoluminescence (PL)

An optical spectroscopy technique that probes radiative recombination under optical excitation. PL reveals band structure and defect states but does not reflect charge injection or device operating conditions.

TRPL decay curves showing different lifetimes

Time-resolved Photoluminescence (TRPL)

A time-resolved extension of PL that measures carrier recombination dynamics after pulsed excitation. TRPL provides excited-state lifetimes but lacks direct information on electrically driven recombination.

Time-resolved emission spectra of tryptophan over nanoseconds

Time-resolved Emission Spectroscopy (TRES)

A spectro-temporal method that records emission spectra as a function of time. TRES complements EL by resolving dynamic spectral shifts and recombination pathways with high temporal resolution.

In-Depth Scientific Resources

Premium Resources

Access in-depth application notes and scientific posters with detailed methods, measurement data, and real-world use cases.

Application Note: TRPL and Electroluminescence Characterization

This application note demonstrates time-resolved photoluminescence and electroluminescence measurements of quantum dot LEDs

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